Teonex®
1.Introduction of Teonex®

After the start of the commercial production of naphthalenedicarboxylic acid (NDC) as the raw material of PEN by the hands of US Amoco Chemical Co. in 1995, the trial of application of PEN resin to molding product field started, and this resin came to be used in various fields. Teijin Group started the research and development of PEN resin in 1964, 31 years precedential to the above event, and it has continuously been engaging without a break in the development of application of the resin to molding material, biaxially-oriented film, and fibrous material. As early as 1971, we commercialized PEN film, and developed a new process for raw material synthesis. It is not an exaggeration to say that the history of PEN development by Teijin is the history of PEN all over the world.

2.Features of Teonex®

PEN is crystalline thermoplastic polyester with the skeleton chain of polycondensation product composed of naphthalenedicarboxylic acid as an acid component and ethylene glycol as a glycol component. It is manufactured in the same way as polyethylene terephthalate (PET) as typical polyester, and injection molding processing is also performed in the same way. However, the performance of PEN is evaluated one rank higher than that of PET. Although PEN is originally crystalline resin, crystalline velocity is slow, and transparent molding product can easily be obtained. For this reason, this resin is utilized as functional members for industrial parts, food packaging, medical product packaging, etc.

<Features of PEN resin>
(1) Transparency is good.
(2) Temperature of deflection under load is high and heat resistance is excellent.
(3) Gas permeation and water permeation are very low.
(4) Chemical resistance and hydrolysis resistance are very strong.
(5) Flavor adsorption is little.
(6) With UV ray screening performance, enveloped contents are protected.
3.Physical Properties of Teonex®
Basic characteristics
Characteristics Test Method Unit PEN
Homopolymer
TN8065S
PEN
Homopolymer
TN8050SC
PET
Specific gravity ASTM D792 1.33 1.33 1.33
Melting point DSC method 265 265 252
Tensile strength ASTM D638 MPa 74 74 55
Flexural strength ASTM D790 MPa 94 94 88
Flexural modulus GPa 2.3 2.2 2.2
Impact strength (Notched) ASTM D256 J/m 39 29 29~49
Deflection temperature under load ASTM D648
(4.6kgf/cm2
109 109 63
Molding Shrinkage ASTM D955 0.4~0.8 0.4~0.8 0.4~0.8
Heat resistance

The heat resistance of a stretch-blow bottle is shown in the following Figure.

The stretch- blow bottle has about 100°C of heat resistance.

Gas permeation property
  Condition O2 CO2 H2O
PEN
(homopolymer)
Non-stretched 18 59 15
Stretched 5.9 24 7
PET Non-stretched 53 263 60
Stretched 23 105 21

 

Conditions: Stretching ratio; 3.5 × 3.5, Measurement temperature; 30°C

Unit: O2, CO2: cc·100 μm/m2/24hr/atm, H2O: g·25 μm/m2/24hr

Chemical resistance
Chemicals Chemicals Chemicals
Nitric acid 10% OK Sodium hydroxide 1% OK Toluene OK
Sulfuric acid 99% Bad Sodium hydroxide 10% OK Xylene OK
Hydrochloric acid OK Saturated aqueous ammonia OK Phenol Bad
Acetic acid OK Hydrogen peroxide OK THF Bad
Formic acid Bad Ethyl alcohol OK Glycerin OK
Citric acid OK Methyl alcohol OK Grease OK
Ethyl acetate OK Acetone OK Motor oil OK
Butyl acetate OK Benzene Bad Gasoline OK
UV transmittance
Hydrolysis resistance
Food sanitation property
  • Japan: Conforms to the various notifications of Food Sanitation Act, and conforms to the positive list of Japan Hygienic Olefin and Styrene Plastics Association.
  • USA: Conforms to FDA CFR §177. 1637 (homopolymer).
               Registered in FDA Drug Master File Type III (TN8065S).
               Usable for various types of food packaging.
  • EU: Conforms to EC Directive 90/128/EEC, 93/9/EEC.
            Both homopolymer and copolymer are usable for various types of food packaging.
Molding processing
Preliminary drying

Prior to injection molding or extrusion molding, drying of the material is necessary. If drying is inadequate, hydrolysis occurs during melting, and inherent characteristics cannot be obtained.

Dryer: Dehumidification dryer, Drying temperature: 160°C, Drying period: 6 hr

Meanwhile, excessively high temperature or long-time drying gives adverse effects on the hue of molding product.

Conditions for injection molding and extrusion molding

Since this resin has high melting point and high melt viscosity, molding should be performed with due consideration of melting characteristics.

Cylinder temperature: 280-310°C

Mold temperature: 15-60°C

Conditions for stretch-blow molding
Preform heating temperature: 130-150°C
Examples of application field
  • Returnable bottle
  • Cosmetic container
  • Plateware
  • Medical product container
  • Blending material for improving PET performance (moisture barrier, gas barrier, heat resistance, UV ray absorption, etc.)
  • Components that requires transparency, heat resistance, or chemical resistance